I was going to write my second user-chooser about something automobilistic, but yesterday’s lecture happened to turn me on to innovative and exciting energy storage solutions, like the one you see here.
(Yes, there will be many battery/”rapid thermal event”/a.k.a. “FIRE” puns; you’ve been warned)
So, batteries.
They’re in lots of stuff nowadays. They aren’t the only energy storage solution ever invented, of course. I could go into a couple more very cool options, like flywheels (the power of a spinning disk), hydroelectric dams (the power of water, going downhill) and electric double-layer capacitors, also know more colorfully as super- or ultracapacitors, which I’ll talk about later. But, it just so happens that Wikipedia probably does a better job at giving a super-broad and super-almost-perfectly-cited overview of the topic, so enjoy at your leisure.
The skinny on batteries: repositories of chemical energy that use (oftentimes eco-unfriendly) electrolytes to transport negative charges from where they want to be to crowded on one side of the battery, setting up a potential difference, or “voltage,” across the battery. This voltage produces an “electromotive force” otherwise known as either (technically) “e.m.f.” or (essentially) “push” which, indeed, pushes electrons along a circuit if the battery happens to be connected to one.
The problem(s, of which there are many): the less obvious problem is the tendency of batteries to be eco-unfriendly. Even the rechargeable ones eventually run out of chemical energy, or have developed what is known as “battery memory” (not charging back up to full charge) sometimes to the point of being utterly useless. Just before I switched out my laptop’s primary battery a month ago, I couldn’t use the laptop while not plugged into the grid because the battery didn’t last long enough to boot up. And you can’t really do much with used up batteries.
Batteries use up many valuable materials in their manufacturing processes, and the processes themselves often involve toxic and dangerous chemicals. Among the dangerous substances contained in various batteries, heavy metals include mercury, lead, cadmium, nickel, zinc, manganese, potassium hydroxide and manganese dioxide. These are not friendly things to be putting directly into the earth as landfill.
From a non-ecological, user-end point of view, batteries are also rather unpleasant. Those suckers are big. And they’re heavy. Take a look at any hi-tech portable electronic device you own; your phone, or, in particular, your laptop. Take out the battery (make sure it’s off first, of course) and notice how light it is. My laptop battery is condensed (only takes up a little under 1/4 of the space in the chassis) but it accounts for more than half the weight of my laptop. Fully one half of the chassis of my phone, a skinny Samsung Blackjack, is taken up by the battery, and once again, the battery accounts for more than half the weight of the device.
If the early 90’s are remembered, among other things, for the ridiculous brick-phones, then the early 21st century will be remembered for its gargantuan batteries in all devices. Even back then, the batteries tended to be the main culprit for the brick-ishness of most “portable” electronics.
It’s not all doom and gloom, however. Part of the reason I wanted to write about this was actually so that I, myself, could feel better about the future of batteries, seeing as how the present seems so gray and sooty. It seemed like batteries weren’t really going anywhere for a while, but wait! The internet reveals all:
According to a January 2008 article from Technology Review, an online technology news site published by MIT, a company called Boston-Power has developed a lithium-ion battery (called the “Sonata”) that can complete 80% of its recharge cycle in only 30 minutes. The article is low on technical details; it essentially alleges a “new shape” and switching in manganese for the typical cobalt oxide cathode were enough for this improvement. That said, it’s very generous with company funding stats, product cost and battery time-to-discharge data. The “Sonata” model batteries also incorporate some fairly significant safety upgrades, including changing the canister from carbon steel to aluminum – which breaks at lower temperatures. This prevents the major heat and pressure buildups that can lead to the oh-so-deliciously euphemized “rapid thermal events” that have been cropping up in the news of late. I tend to trust TR’s articles, and this one alleges that the battery maker is in “in discussions” with the big notebook companies of the world, so this looks like a good short-term bet.
I mention trust because I also stumbled upon this article from PhysOrg.com, which has interesting articles, but seems a little less reputable. This article alleged that Toshiba had developed a “nanobattery” that recharged to 80% capacity in 1 minute. Needless to say, I found this to be a questionable claim.
I was even more surprised to find a press release from Toshiba itself backing this claim. It’s official-looking and everything, with a fun and somewhat obviously jargon-y graphic that you see somewhere around here. Until I find further confirmation of this marvelous breakthrough, however, I’m going to call it an amusing locker-room-worthy case of exaggeration, since both the article and the press release are dated March of 2005. That’s three years ago, for those counting, and no more sign on the ‘tubes of any superbattery being developed in Toshiba’s secret underground mountain lab/lair.
A more long-term development to look forward to, however, would be the modestly-termed ultracapacitor.
Capacitors, unlike batteries, store energy in electric fields, not in chemical suspension. If you charge two metal plates with opposite polarities (one negative and one positive) and orient them so that they are facing each other from a very small distance, but aren’t touching, there will be an electric field set up between them. The concept of storing energy in an electric field is a little abstract for those who haven’t taken a physics class in a while, but I won’t attempt to explain it with a weak and misleading metaphor (if your curiosity burns, Wikipedia is there for you).
In short, however, the advantages of capacitors are thus: unlike electrochemical batteries, ultracaps can take up and release large amounts of charge very quickly, and for many more cycles than the traditional rechargeable battery – the only wear on capacitors is structural and environmental, not chemical and certainly not part of normal operating conditions, so they last longer. On the green side of things, capacitors do not include as many toxic substances in their manufacture, and are quite a bit more long-lasting than traditional batteries. If they were able to replace batteries, the ever-so-traditional cradle-to-grave paradigm epitomized by disposable battery use would be stopped in its tracks.
The downside of normal capacitors is that they can’t match batteries in terms of total capacity for storing charge per unit area (the amount of charge a capacitor can store is directly proportional to its surface area). So capacitors are much faster than batteries at charge transfer, and are more reliable and durable, but can’t store as much charge, and thus, energy.
As always, however, there are ways of getting around problems: at least two companies have proposed, prototyped and are (presumably) testing their respective “ultracapacitors” which share all the advantages of normal capacitors, while making up for their disadvantages vis-a-vis electrochemical batteries – and in some cases surpassing them altogether.
One Texas company called EEStor, has designed an ultracap with a new dielectric material (an insulating substance that separates the charged plates, which can be engineered such that it increases the energy storage capacity of the capacitor). The seeming wonder-substance, a ceramic powder, is called “barium titanate”. According to the company, its system “… claims a specific energy of about 280 watt hours per kilogram, compared with around 120 watt hours per kilogram for lithium-ion and 32 watt hours per kilogram for lead-acid gel batteries” (quoted from the above-linked January 2007 article). The company already has a partnership with a small Canadian electric car company (ZENN Motor), and expects to sell them their power storage system for use in their light cars. The article indicates that there is considerable skepticism about the company’s claim, but if they’re con artists, then they’re the best damned ones out there for fooling Kleiner Perkins Caufield & Byers into backing them. It wouldn’t be the first mistake that venture capital has made, but I think it’s safe to say that Kleiner Perkins knows their business pretty well, and where there’s smoke, there may well be fire. EEStor is a company to be watching.
In another twist on ultracapacitors, the MIT Laboratory for Electromagnetic and Electronic Systems (LEES) is using the ever-more-useful carbon nanotube to increase the energy capacity of traditional capacitors.
Their process is fairly straightforward to explain: using the regular geometry of nanotubes (i.e. they’re straight) and the fact that nanotubes are one-thirty-thousandth the diameter of a human hair and can be made to be 100,000 times as long as they are wide, the scientists have effectively managed to squeeze a lot more “parallel plate” area from the total available volume in a capacitor housing, thus increasing its energy capacity. It’s nothing more than using nano-scale control over geometry to get every penny’s worth of surface area from these new ultracaps. There are no blockbuster numbers included in the cut-and-dry news release (dated, incidentally, from February of 2006) which makes me think that is is the most promising of all the “ultracapacitor” promises I’ve seen to date.
In conclusion (finally): new (less stone-aged) battery technologies are coming, and much more eco-friendly eletrochemical-battery-replacement technologies are following not quite hot on their heels. They most certainly cannot get here soon enough.